martes, 6 de mayo de 2008

BASIC DEFINITIONS ON HOW TO MAKE EMULSIONS

When two liquids are immiscible but do not separate immediately they are said to form an emulsion. Some emulsions are quite stable and will take a long time to separate. For example milk is an emulsion of water and fat but is fairly stable. Other emulsions may separate quite quickly, for example a simple salad dressing of oil and vinegar will separate almost immediately (note that vinegar is water based).
The emulsion itself consists of small droplets of one liquid within the body of a second liquid. An emulsion containing droplets of oil in water is called an oil-in-water emulsion and the oil is called the dispersed phase while the water is called the continuous phase. An emulsion with droplets of water in oil is called a water-in-oil emulsion. A good oil-in-water emulsion will consist of very fine oil droplets homogeneously dispersed throughout the body of water.
Since colas are oil-in-water emulsions this discussion of emulsions assumes that an oil phase is being dispersed within a water phase. In practice neither the water phase nor the oil phase of an emulsion are likely to be pure substances. For example in colas the continuous water phase is an acidic solution of citric or phosphoric acid together with other ingredients such as caramel and sugar, the oil phase is a complex mixture of organic molecules from the essential oil flavourings. In general the water soluble molecules all stay in the water phase and the oil phase will be a mixture of all the liquid molecules that are not soluble in water (i.e. a mixture of oils).
FOR COMPLETE ARTICLE GO TO: http://sparror.cubecinema.com/cube/cola/chemistry/cola1.htm#top

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GREEN CHEMICALS

The Green Seal certification is granted by the organization with that name and has a great number of members contributing with the requirements to pass a raw material or a chemical product as "green". Generally for a material to be green, has to comply with a series of characteristics like: near neutral pH, low volatility, non combustible, non toxic to aquatic life, be biodegradable as measured by oxygen demand in accordance with the OECD definition.
Also the materials have to meet with toxicity and health requirements regarding inhalation, dermal and eye contact. There is also a specific list of materials that are prohibited or restricted from formulations, like ozone-depleting compounds and alkylphenol ethoxylates amongst others. Please go to http://www.greenseal.com/ for complete information on their requirements.
For information on current issues regarding green chemicals, see the blog from the Journalist Doris De Guzman, in the ICIS at: http://www.icis.com/blogs/green-chemicals/.
Certification is an important — and confusing — aspect of green cleaning. Third-party certification is available for products that meet standards set by Green Seal, EcoLogo, Energy Star, the Carpet & Rug Institute and others.
Manufacturers can also hire independent labs to determine whether a product is environmentally preferable and then place the manufacturer’s own eco-logo on the product; this is called self-certification. Finally, some manufacturers label a product with words like “sustainable,” “green,” or “earth friendly” without any third-party verification.
“The fact that there is not a single authoritative standard to go by adds to the confusion,” says Steven L. Mack M.Ed., director of buildings and grounds service for Ohio University, Athens, Ohio.
In www.happi.com of June 2008 edition, there is a report of Natural formulating markets that also emphasises the fact that registration of "green formulas" is very confused at present, due to lack of direction and unification of criteria and that some governmental instittion (in my opinion the EPA) should take part in this very important issue.