Work Continues on Antimicrobial Solutions for Food Safety
Antimicrobial solutions have proven to be very good at treating certain contaminants on animal carcasses and on primal and subprimal cuts, says Jim Dickson, professor in the Department of Animal Science, Inter-Departmental Program in Microbiology at Iowa State University in Ames.
“It’s one of the more significant introductions … in meat and poultry in the last 25 years,” he says. The statistics support that fact as well: Antimicrobial solutions are working.
According to U.S. Department of Agriculture data for poultry, the Salmonella incidence rate has been reduced 26 percent from the beginning of 2013 and 55 percent compared to five years ago. Further, data indicate that the number expressed as a Most Probable Number of Salmonella is very low – fewer than 10 microorganisms when a positive result is enumerated, Ewing says.
One of the biggest challenges for processors of ready-to-eat (RTE) products that are exposed to the environment at packaging is the potential for Listeria monocytogenes contamination, explains Lynn Knipe, extension processed meats specialist and associate professor in Food Science and Technology, and Animal Sciences at Ohio State University in Columbus.
“For intact fresh cuts and for ready-to-eat products, surface contamination has been the greatest concern for processors, and I don’t see that changing in the near future,” Knipe says. “Since this is a surface contamination, sprays and dips can have the greatest impact on the surface contamination.”
Gaining ground
Newer compounds and application strategies are being developed for antimicrobial solutions. Lauric arginate, for example, was introduced in the United States a few years ago as an effective antimicrobial spray against Listeria.
“Lauric arginate may be sprayed directly on to RTE meat products prior to packaging, or sprayed inside the pouch before the meat product is inserted into the package,” Knipe says. “The latter option relies on the vacuum to distribute the lauric arginate uniformly around the packaged product. More recently, it has been shown to be effective as a surface treatment to eliminate Salmonella on chicken.”
Peroxyacetic acid is a new chemical that’s been widely used, especially in the beef industry, Dickson says. In the poultry industry, carcass washers apply sprays to both the inside and outside of the body cavity, as well as to the external surfaces, he says. One of the newest advancements in some poultry plants has been the use of a wash after the carcasses come out of the chiller.
“If you spray an organic acid on a poultry carcass and then you put it into a chiller, then it pretty much washes all of that off,” Dickson says. “There have been some that are using a wash or spray cabinet after carcasses come out of the chiller, and that seems to be pretty effective.”
The compounds commonly used today are considered processing aides and do not have a residual effect. If a residual effect was present, the compound would be considered an ingredient and would have to be included on the label.
Nevertheless, some clean-label products, which involve vinegar and lime juice, have been developed that are effective in eliminating surface contamination of both Listeria monocytogenes and Clostridium perfringens on RTE meat products, Knipe says.
“With the consumer pressure for clean labels, these products provide the product safety needed [for processors and consumers], without chemical names that concern consumers,” he says.
Additionally, much work is being done in spices, botanicals, phyto-antimicrobials and phyto-chemicals to see if compounds can be isolated from various plants and/or seeds to have great antimicrobial effects, says Robert Gravani, a professor of food science in the Department of Food Science at Cornell University in Ithaca, NY.
“Certainly one of the areas that is being actively researched is the synergies that may develop between antimicrobials that are used in concert with each other,” he says. Research also needs to continue on antimicrobials to make sure they are still effective against the organisms to which they are targeted, he adds.
“Clearly one of the things in people’s minds is, ‘Will there be new compounds coming in the future that will be even more efficacious than what we have now?’” Gravani says. “We’ve got to be constantly prospecting toward new compounds that will work that are as effective or more effective than the ones we have today.”
In addition, Ewing says, multiple points in each process are being evaluated for application effectiveness.
“The majority of these revolve around a water-based application, but other technologies are also being evaluated, such as UV light and high-pressure pasteurization,” she says. Antimicrobial solutions are being applied in more points during processing as well.
For example, when organic acids first came out for beef carcass washes, they were only applied at the end of the process after the final carcass wash, Dickson says. Then some companies started applying them pre-evisceration, which is now pretty standard in the industry, he says. Now, companies are spraying carcasses when they come out of the coolers.
“In some cases, they are getting treated as many as three times with some of these antimicrobial solutions,” Dickson says. “It’s all with the idea of reducing the potential of contamination on the surface of the animal.”
However, the cost of some of these antimicrobial products may be keeping some processors from using them on their products, Knipe adds. Still, the industry continues to look for new compounds and methods of antimicrobial wash application. As technology improves, so will the ability of these compounds to reduce microbial contamination.
However, Ewing reminds that, while antimicrobial compounds can help reduce the level of microbes to almost undetectable levels, the product is not sterile. Safe food-handling techniques must be employed at all times when handling raw food.
(“Work Continues on Antimicrobial Solutions” by Elizabeth Fuhrman first appeared in The National Provisioner on December 6, 2013. Courtesy of The National Provisioner.)
martes, 8 de abril de 2014
BIOCIDES FOR FOOD
jueves, 20 de febrero de 2014
DISINFECTION
Disinfecting is more important than cleaning – Ultimately, infection control comes down to efficient cleaning practices and not simply applying a disinfectant. The physical removal of a "germ" is much more important than the chemical destruction of it. A good example of this is: You are at a picnic...you drop part of a sandwich on the ground...before you know it you are being invaded by ants. Now, if you want to take the "disinfectant" approach you can simply spray insect spray on the ants. The ants will die, but you will find that more ants will return from another angle.
Now if you do the right thing by picking up the sandwich and placing it in the trash, or "cleaning” it from the area, you will have eliminated the food source and thus ultimately stopping and preventing the problem.
• Hospital Grade disinfectants require a TB claim – A “Hospital Grade” Disinfectant only requires 2 organisms to be tested: Pseudomonas aeruginosa and Staphylococcus aureus.
In fact, tuberculocidal disinfectants are not used to control the spread of TB; the TB claim is only used as an indicator of strength. TB is transmitted only by the airborne route, meaning that the only way this disease is spread is by infected people coughing and sneezing tiny infected droplets into the air and others breathing those droplets into their lungs. Therefore, surface cleaners and disinfectants will have no impact on the spread of this pathogen.
• Bleach is the ultimate disinfectant. In order for bleach to function properly as a disinfectant or sanitizer the surface MUST be precleaned prior to the application of bleach. (NO if, ands, or buts about it.) Disinfecting and sanitizing with bleach is a two-step process.
Bleach's shelf life is unstable. Depending on the age and storage conditions, the actual amount of active chlorine will vary. Sodium hypochlorite a.k.a. bleach will break down into salt and water. Never store bleach in warm areas. Because of this the following are true:
o A fresh solution of bleach must be made prior to disinfection or sanitation. (Water ions or hardness and soil contaminants from a dirty container can adversely affect available chlorine ppms)
o Only an E.P.A. registered bleach product can be used for disinfection or sanitation.
• Microorganisms are becoming resistant to disinfectants or disinfectants are promoting antibiotic resistance in microorganisms - The mode of action for a disinfectant is different than the mode of action of an antibiotic. For example – if antibiotics are like poison to a bacteria, then disinfectants would be like a shotgun. The same thing that protects you from poison would not protect you from a shotgun.
This same scenario applies to antibiotic resistant bacteria (think MRSA or CRE). Antibiotic resistant bacteria have developed a resistance to a type of antibiotic; the ability of a bacteria to be resistant to an antibiotic has no direct indication of the efficacy of a disinfectant for that same bacteria.
There are many misconceptions associated with cleaners and disinfectants in healthcare settings, some include:
• Kill time is the same as wet time. This is untrue—the time it takes a product to eliminate microorganisms is not necessarily the same as the time it is able to keep a surface wet.
• Fast “overall” kill times are best. While fast kill times are important, what the product kills is more important. Some manufacturers may leave off tough-to-kill organisms in order to achieve a fast overall kill time. For example, if it takes a certain product 5 minutes to kill Norovirus, but the manufacturer wants to keep the overall product kill time to 3 minutes, they may leave Norovirus off the label all together.
• All products will react the same on surfaces. Different ingredients and different formulas will react differently with different surfaces. And just because two products may have the same active ingredient doesn’t mean they will necessarily have the same interactions with surfaces. For example, some products contain special corrosion inhibitors in their formulas to provide enhanced surface compatibility.
• Residue is bad. Usually residue left behind on a surface by a product is due to dissolved ingredients in the formula that dry on the surface as solids. These are often important ingredients, such as detergents for more powerful cleaning, corrosion inhibitors for protecting surfaces, or stabilizing agents to maintain product shelf life. To protect surfaces, avoid residue buildup by periodically removing it with a clean, damp cloth.
• The more chemical, the better. Cleaning and disinfecting products are formulated for use in specific amounts and concentrations. When mixing or diluting products, it is important to closely follow the manufacturer’s instructions to avoid potentially hazardous situations.
• Bleach contains chlorine gas. This is untrue. Sodium hypochlorite is the active ingredient in bleach disinfectants.
• Bleach odor is harmful. Multiple studies have shown that when exposed to bleach, little or no concern about the odor of bleach was expressed by patients, families or staff. EPA-registered bleach disinfectants are formulated well below the levels recognized to cause potential respiratory irritation or overt health effects. Bleach is not a recognized asthmagen by any regulatory agency.
• Bleach is bad for the Environment. Sodium hypochlorite breaks down rapidly into salt and water in the environment and has no negative impact on the environment. According to the EPA, “currently registered uses of the hypochlorites will not result in unreasonable adverse effects to the environment. –
viernes, 7 de febrero de 2014
The Science Of Odor Control
lunes, 30 de septiembre de 2013
THE SHIFT FROM MSDS TO SDS FOR GHS
Manufacturers Make The Switch To GHS Labels, SDS Sheets
By Stephanie S. Beecher, Associate Editor
“Manufacturers have a lot of latitude in how they make [chemical label] descriptions but with the new standard it is much more prescriptive,” says Bill Balek, director of legislative affairs at the ISSA. “Before they re-label they have to reclassify their products. We’re using a different scheme of stratifying the products and they are very detailed.”
Besides changing labels, the revised safety data sheets require information to be presented in a 16-section sequence. Before GHS, OSHA allowed either its eight-section format or ANSI’s 16-section format to be used. Now, the SDS will be similar to ANSI’s version with the requirement that the sections be presented in a strict order. Formerly, the document’s format was left up to manufacturers.
The required order is as follows: Identification, Hazard’s identification, Composition/information on ingredients, First Aid measures, Fire-fighting measures, Handling and Storage, Exposure controls/personal protection, Physical and chemical properties, Stability and reactivity, Toxicological information, Ecological information, Disposal considerations, Transport information, Regulatory information, and Other information, including date of preparation or last revision.
Casavant expects the changes to SDSs and chemical labels to present an ongoing challenge to employers, as they attempt to bring their inventory into compliance.
“I think it’s safe to say that folks are stressed,” he says. “People are quite concerned about the workload this new standard will bring. [Employers] suspect some chemical manufacturers will take their time in complying and that will create issues for end users downstream.”
lunes, 16 de septiembre de 2013
BACTERIA/ ENZYMES IN YOUR CLEANERS
To understand how enzyme cleaners — also known as bio-enzymatic cleaners — can be advantageous in restroom cleaning, custodial managers need to first understand what they are and how they work.
“Some managers train their people to go in and spray enzymes to take care of odors and then use disinfectant on top of that,” says Cadell. “In these cases, they’ve killed the product before it’s even had a chance to work.”
jueves, 5 de septiembre de 2013
Scale Build Up in Water Pipes
Scale usually refers to an intimate mixture of sparingly soluble mineral salts. Mineral scale deposition occurs because of heat transfer or pressure changes. Calcium carbonate scaling from hard water, and calcium phosphate and oxalate formation in sugar refineries are examples. Other types of fouling include the growth of algae and bacteria (bio-fouling), the consolidation of loose particles (particulate fouling, i.e. corrosion by-products), and the accumulation of “coke” like deposits (e.g. chemical reaction fouling).
What can go wrong?
Calcium carbonate is the predominant component of the hard and tenacious scale deposit from water and is particularly apparent in processes involving heat transfer. A concentration of dissolved solids by repeated partial evaporation of the water is the main factor that causes calcium carbonate scale. Even soft water will eventually form scale when concentrated numerous times.
The formation of a thin uniform layer of scale or wax can temporarily reduce steel corrosion but eventually stagnant conditions develop under the deposit and electrochemical reactions will corrode the steel surfaces. The result can be fluid leaks and equipment failure, which are potentially very dangerous. In the food industry, the incorporation of even undesirable trace particulates can lead to off-flavors or off-colors, reducing shelf life, or even making the product unsalable.
Not only are plant and product integrity at risk but also personnel health and safety may be compromised. Fouled safety valves or emergency process sensors may not operate in an emergency. Overheated boilers have been known to explode. Failure to control bacterial growth in cooling water can create conditions hazardous to health (e.g. production of Legionella pneumophila) or, in anaerobic conditions, may allow the production of toxic hydrogen sulfide from sulfate reducing bacteria.
Recognizing fouling
Because scales and other deposits generally form inside closed systems, it is not always evident that deposition is occurring. Nevertheless, some clues can provide the necessary evidence. It is useful to try to answer the following questions:
Are energy/heating bills reduced immediately after cleaning the plant?
Is it necessary to arrange significant planned and/or unplanned downtime?
Are heat exchangers performing below design?
Is corrosion a problem in the plant?
Are there signs of unexpected deposit formation within the system?
A process audit would identify the extent of the current problem, the point in the system corresponding to initial fouling, and most useful, why there is a problem. From the evidence collated, it may be possible to suggest a solution without the need for expensive external control measures. Minor changes in the process temperature, pressure, pH or fluids composition could significantly reduce the fouling potential at practically no cost.
Although it is usually possible to find a chemical solution to a fouling problem, ever increasing environmental and safety pressures demand that chemical consumption be reduced wherever possible. Increasingly, restrictions are being applied regarding the use of chemicals, due to their environmental impact. However it has proven to be the best solution to keep the systems clean. If the scale has develop, there is a need to descale with an acid solution; then it is usually neutralized, and the system replenished with water and a close loop additive incorporated, to maintain the pH in conditions as to prevent scale formation again, and to keep rust and oxidation out. As a rule of thumb, if scale build up is the problem, the pH of the solution should be kept lower than 7, if the problem is corrosion, then the pH of the solution should be above 8.
Physical methods
A range of physical methods can be used to remove fouling deposits. Water jetting, sand or plastic-bead blasting can be used in accessible locations. Such methods are expensive and can cause abrasion of surfaces.
Magnetic and electronic
Unlike other preventative techniques, electronic descaling devices do not stop precipitation but alter the shape of the crystals to reduce the adherence and build-up of deposits on the pipe wall.
miércoles, 28 de agosto de 2013
Bacteria in Drinking Water
News | August 14, 2013
Bacteria In Drinking Water Are Key To Keeping It Clean
Research at the University of Sheffield, published in the latest issue of Water Science and Technology: Water Supply, points the way to more sophisticated and targeted methods of ensuring our drinking water remains safe to drink, while still reducing the need for chemical treatments and identifying potential hazards more quickly.
The research team, from the University of Sheffield's Faculty of Engineering, studied four bacteria found in the city's drinking water to see which combinations were more likely to produce a 'biofilm'. Biofilms are layers of bacteria which form on the inner surfaces of water pipes.
"Biofilms can form on all water pipes and as these are usually non-harmful bacteria, they don't present a problem," explains lead researcher, Professor Catherine Biggs. "However, biofilms can also be a safe place for harmful bacteria such as Escherichia coli or Legionella to hide. If the bacterial growth is too heavy, it can break off into the water flow, which at best can make water discoloured or taste unpleasant and at worst can release more dangerous bacteria. Our research looks at what conditions enable biofilms to grow, so we can find ways to control the bacteria in our water supply more effectively."
Funded by the Engineering and Physical Sciences Research Council, the research isolated four bacteria from water taken from a domestic tap: two were widely found in drinking water everywhere, one was less common and one was unique to Sheffield. The researchers mixed the bacteria in different combinations and found that, in isolation, none of them produced a biofilm. However, when any of the bacteria were combined with one of the common forms, called Methylobacterium, they formed a biofilm within 72 hours.
"Our findings show that this bacterium is acting as a bridge, enabling other bacteria to attach to surfaces and produce a biofilm and it's likely that it's not the only one that plays this role," says Professor Biggs. "This means it should be possible to control or even prevent the creation of biofilms in the water supply by targeting these particular bacteria, potentially reducing the need for high dosage chemical treatments."
Domestic water supplies in the UK are regularly tested for levels of bacteria and, if these are too high, water is treated with greater concentrations of chlorine or pipe networks are flushed through to clear the problem. However, the standard tests look for indicator organisms rather than the individual types which are present. Testing methods being developed by the Sheffield team – as used in this research – involve DNA analysis to identify the specific types of bacteria present.
"The way we currently maintain clean water supplies is a little like using antibiotics without knowing what infection we're treating," says Professor Biggs. "Although it's effective, it requires extensive use of chemicals or can put water supplies out of use to consumers for a period of time. Current testing methods also take time to produce results, while the bacteria are cultured from the samples taken.
"The DNA testing we're developing will provide a fast and more sophisticated alternative, allowing water companies to fine tune their responses to the exact bacteria they find in the water system."
SOURCE: University of Sheffield
viernes, 9 de agosto de 2013
SICK BUILDING SYNDROME
Indoor Air Quality: Clearing The Air By Ronnie Garrett Ever gotten complaints from building occupants that they felt better before they arrived at work and again after they left? And it wasn't because they disliked the job but because the building was making them sick? There's a name for it — it's called sick building syndrome. In this condition, building occupants complain of symptoms such as sensory irritation of the eyes, nose and throat; neuro-toxic or general health problems; skin irritation; nonspecific hypersensitivity reactions; and odor and taste sensations. These symptoms are often pinned to flaws in the heating, ventilation and air-conditioning systems. Other factors include contaminants produced by the off gassing of building materials, volatile organic compounds (VOCs), molds, byproducts of office machinery, light industrial chemicals and more. While the long-term affects of exposure remains an emerging science, there is much custodial workers can do to reduce their exposure, and that of others, by improving indoor air quality (IAQ). There are three primary means of exposure: Inhalation, ingestion and skin contact. When custodial managers consider all three routes, they expand their thinking to all factors that might impact IAQ. "Many times people think indoor air quality is only about chemicals and VOCs. But when you think of it more broadly in terms of what people can inhale, ingest or touch, it's also particles, dust and other contaminants," says Steve Ashkin, president of The Ashkin Group, Bloomington, Ind. "There are three basic things people have to be worried about: Chemicals, VOCs and dust particles, especially the really small ones which are tiny enough to inhale deeply into the lungs." Stop It At The Source According to Allen Rathey, president of The Healthy Facilities Institute (HFI), Boise, Idaho, there are three main ways to improve IAQ: (1) Stopping contamination at the source, (2) Better ventilation, and (3) Cleaning the air itself. The best approach, he says, is to stop contamination at the source. He likens airborne contamination to an oil spill. Once oil gets into the environment, it quickly dissipates and spreads. "It's better to stop an oil spill before it starts, and it's the same with air contamination," he says. "By the time you get to step two or three, you're at the tail end of contamination." Stopping contaminants at the source requires a solid understanding of what the sources of contamination are. For example, consider the contaminants walked in on a person's shoes. These particles include dust generated by industrial facilities, pesticides and more, which is present in soil and on city streets and sidewalks. "If you keep that dust from coming into the building, you stop one source of contaminants," says Rathey. How might this be accomplished? By washing sidewalks and parking lots near building entrances, then putting large walk-off mats inside and outside every doorway. This matting must allow a sufficient number of steps to occur in order to ensure dust falls off shoes and onto the mats. "We can keep a lot of nasties out of the air just by making sure our cleaning program has a sidewalk maintenance component and great entrance matting," Rathey stresses. Suck It Up Next is to make sure equipment actually removes, rather than redistributes dust and other contaminants. Vacuum cleaners deserve primary consideration, says Carpet and Rug Institute (CRI) President Werner Braun. "There are vacuums out there that blow stuff back into the air because their housing is poorly designed," he explains. CRI simplifies vacuum selection through its Seal of Approval Program. This program rates vacuums on soil removal, dust containment and safety to carpet surfaces. "The Seal of Approval is the only quantifiable testing program for vacuums in the world," says Bethany Richmond, CRI communications manager. "We test vacuum cleaners to see if they work, are low emitting and don't destroy the carpet." When targeting IAQ concerns, Braun recommends cleaning operations choose vacuums with CRI Seal of Approval Gold certification. This certification ensures a vacuum removes and holds particles as small as 35 micrograms. And that's a good thing, says Ashkin, who points out that it's the fine particles (smaller than 0.3 microns) that humans inhale deeply into their lungs. "If you select a vacuum that has been evaluated in this way, you know that you are keeping the dust you pick up inside the vacuum," Rathey says. "You need a vacuum that's going to remove more and release less." Ian Grieg, CEO of Daniels Associates, in Phoenix, also recommends walk-behind vacuums or walk-behind sweepers for hard surfaces, as well as carpets. "Other countries have been vacuuming their hard-surface floors since the 1980s," he says. "We still don't vacuum hard-surface floors and that's one of the largest causes of poor IAQ because dust mops just throw particles into the air." But if this equipment — be it high-quality walk-behind, upright or backpack vacuums — is improperly maintained, it can contribute to IAQ concerns rather than address them. Vacuums use airflow to suck up particles but if clogged filters and nearly full bags reduce airflow, then fewer particles are picked up. "The beater brush is no longer driving dust into the vacuum as much as it is pushing it into the air," Rathey adds. Grieg says proper vacuum maintenance is a common problem across the custodial industry. Cleaners need to be taught to use high-filtration bags and change them regularly, he says. "The rule of thumb is to empty bags when they are half full, but manufacturers may recommend changing them when they are half, two-thirds or three-quarters full," Ashkin says. "It's never when they are so full they cannot hold anymore." A comprehensive carpet care program also improves indoor air quality. Carpets should be vacuumed daily and shampooed one to four times a year, says Grieg. When shampooing the carpet, make sure carpets dry out within 24 hours to keep mold issues at bay. "Mold and other organic materials require moisture to grow," Ashkin explains. Wipe It Up When dusting with cloths or mops, it's best to go the microfiber route. "Cleaning operations need microfiber wipes for all dusting, damp wiping and damp mopping," says Grieg. But heed this warning: Not all microfiber is created equal, Ashkin advises. No standards exist to ensure microfiber products meet exacting specifications. Cleaning operations need high-quality microfiber products that capture fine particles as opposed to cheap ones that do little more than flick dust into the air. "Look at the product's weight," says Ashkin. "There is a correlation between the weight of the cloth and the quality." And pick the right microfiber for the job. Differing microfiber blends exist and some do a better job with specific tasks than others. "The product will vary whether they are doing dry dusting or wet cleaning," Ashkin says. "They need to use the right microfiber for the application." Chemical Selection Using the wrong cleaning chemicals also can adversely impact air quality. It's important for cleaning operations to carefully weigh their chemical options and select environmentally preferable products, Ashkin says. "We should make an effort to minimize the VOCs in our cleaning products; we should not be contributing to the problem," he adds. Go with fragrance-free products and weigh disinfectant choices carefully, advises Rathey. "These products use petrochemicals and they are very suspect in contributing to IAQ problems," he says. "Quats, for example, have been associated with asthma." Sanitizers and disinfectants also contribute to healthier environments so they do have their place in cleaning, but their harmful affects can be mitigated by how they are used. For example, an aerosol disinfectant adds chemical to the air, but a squeeze bottle solution, where cleaners squeeze a stream directly onto a cloth, can alleviate this problem. Apply these products with a microfiber cloth or mop and IAQ improves again because custodians use less chemistry to clean. "Microfiber allows the use of less corrosive chemistries because it physically removes contaminants," says Grieg. Training And Teamwork "Training is the key to improving IAQ," adds Ashkin. Cleaners need to be taught to select the right product and equipment for the job and to use it correctly. At Daniels Associates, every spec includes a task number, the name of the task, the types of chemicals and equipment needed to perform the task and the results to be expected. "Cleaners need to be taught how to use chemicals and how to use equipment; equipment is a lot more technical than it used to be," Grieg emphasizes. "In the old days the equipment custodians used on the job were the same tools they used to clean at home. It's different now." Teaming with facility managers to ensure heating and cooling systems work with cleaning operations, rather than against them, also improves IAQ. "Why aren't cleaning folks talking with the people who take care of the heating and cooling systems?" Rathey asks. "If we're going to have a seat at the table of healthy indoor environments, we have to understand what's going on in the buildings regarding air flow and heating and cooling systems."
ODOR CONTROL
viernes, 19 de julio de 2013
HAND SANITIZER USAGE
Study Reveals Hand Sanitizer Efficacy
To address this question of efficacy, a study was done to determine hand coverage of three hand rubs — one gel based on 70 percent ethanol, one gel based on 85 percent ethanol, and one foam based on 70 percent ethanol. Each was applied with various volumes — all products: 1.1 mL, 2 mL, 2.4 mL, 1 push and 2 pushes; only foam product: 1.1 mL foam, 2 mL foam, 2.4 mL foam.
Fifteen subjects applied each product, which were supplemented with a fluorescent dye, after which researchers used a UV light to determine the quality of coverage. The hands of 12 subjects per experiment were artificially contaminated with Serratia marcescens and the products applied as recommended (1.1 mL for the products based on 70 percent v/v ethanol; 2 mL for the product based on 85 percent w/w ethanol).
Researchers presented their findings in a presentation titled "Lesser and lesser — the impact of small volumes in hand disinfection on quality of hand coverage and antimicrobial efficacy" at the International Conference on Prevention and Infection Control (ICPIC 2013). The results were:
"A volume < 2 mL yielded a high rate of incomplete coverage (76% - 87%), a volume ≥ 2 mL revealed better results (18% - 40%). There was a significant difference between the five volumes used with all hand rubs (p < 0.001; analysis of variance) but not between the three hand rubs themselves (p = 0.442). Application of 1.1 mL of the hand rubs based on 70% ethanol yielded a log10-reduction of 1.85 or 1.60 log10 (ASTM E 1174-06) and failed the US FDA efficacy requirement. Application of 2 mL of the hand rub based on 85% ethanol reduced the contamination by 2.06 log10 (ASTM E 1174-06) and fulfilled the US FDA efficacy requirement. Similar results were obtained according to ASTM E 2755-10."
In conclusion, the researches found that hand rubs based on 70 percent ethanol and recommended with a volume of 1.1 mL per application are not suitable to ensure complete coverage of both hands and do not fulfill the current ASTM efficacy standard requirements.
Vistas de página en total
GREEN CHEMICALS
Also the materials have to meet with toxicity and health requirements regarding inhalation, dermal and eye contact. There is also a specific list of materials that are prohibited or restricted from formulations, like ozone-depleting compounds and alkylphenol ethoxylates amongst others. Please go to http://www.greenseal.com/ for complete information on their requirements.
For information on current issues regarding green chemicals, see the blog from the Journalist Doris De Guzman, in the ICIS at: http://www.icis.com/blogs/green-chemicals/.
Certification is an important — and confusing — aspect of green cleaning. Third-party certification is available for products that meet standards set by Green Seal, EcoLogo, Energy Star, the Carpet & Rug Institute and others.
Manufacturers can also hire independent labs to determine whether a product is environmentally preferable and then place the manufacturer’s own eco-logo on the product; this is called self-certification. Finally, some manufacturers label a product with words like “sustainable,” “green,” or “earth friendly” without any third-party verification.
“The fact that there is not a single authoritative standard to go by adds to the confusion,” says Steven L. Mack M.Ed., director of buildings and grounds service for Ohio University, Athens, Ohio.
In www.happi.com of June 2008 edition, there is a report of Natural formulating markets that also emphasises the fact that registration of "green formulas" is very confused at present, due to lack of direction and unification of criteria and that some governmental instittion (in my opinion the EPA) should take part in this very important issue.



